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متن کامل


اطلاعات دوره: 
  • سال: 

    2014
  • دوره: 

    10
تعامل: 
  • بازدید: 

    141
  • دانلود: 

    0
چکیده: 

DUE TO THE DEPLETION OF FOSSIL FUEL RESOURCES AND SERIOUS GLOBAL WARMING EFFECTS IN THE LAST FEW YEARS, IT IS VITAL TO REPLACE PRESENT ENERGY CONVERSION TECHNOLOGY AND RESOURCES WITH A MORE SUSTAINABLE/RENEWABLE ENERGY SYSTEM [1]. SOLID OXIDE FUEL CELLS (SOFCS) WHICH ARE ONE OF THE CLEANEST AND MOST EFFICIENT ENERGY CONVERSION TECHNOLOGIES, HAVE ATTRACTED A GREAT DEAL OF ATTENTION RECENTLY AS A SUBSTITUTION FOR TRADITIONAL FOSSIL FUEL CONVERSION SYSTEMS. A CHALLENGING ISSUE IN THE DEVELOPMENT OF SOFCS IS TO IMPROVE Cathode PERFORMANCE BY MINIMIZING Cathode POLARIZATION RESISTANCE TO THE OXYGEN REDUCTION REACTION [2-4]. IN THIS STUDY, SMALL LOADING OF CERIA-BASED CATALYTIC NANOPARTICLESALONG WITH CATALYTICPALLADIUM NANOPARTICLES WERE CO-INFILTRATED INTO THE POROUS STRUCTURE OF LA0.8SR0.2MNO3 (LSM) Cathode BACKBONE AND THE ELECTROCHEMICAL PERFORMANCE OF THE CELLS WAS EVALUATED AT INTERMEDIATE TEMPERATURE RANGE OF 600-800OC. Cathode PERFORMANCE WAS INVESTIGATED BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY (EIS) AND DC POLARIZATION TECHNIQUE (CHRONOPOTENTIOMETERY) AT DC BIAS OF 200 MA/CM2 ON Cathode HALF CELLS. THE RESULTS INDICATED THAT ELECTROCHEMICAL PERFORMANCE OF CO-INFILTRATED Cathode IS SIGNIFICANTLY IMPROVED COMPARED WITH THAT OF LSM CathodeS SEPARATELY INFILTRATED WITH PD AND CERIA-BASED NANOPARTICLES. SCANNING ELECTRON MICROSCOPY (SEM) STUDIES SHOW RANDOM DISTRIBUTION OF DISCRETE NANO CATALYSTS IS FORMED IN THE VICINITY OF Cathode INTERFACE WHICH PROVES EFFECTIVENESS OF THE INFILTRATION TECHNIQUE FOR PERFORMANCE ENHANCEMENT OF Cathode ELECTRODES. LONG TERM STABILITY TESTS ARE IN PROGRESS TO EVALUATE AGGLOMERATION BEHAVIOR OF THE PD CATALYST IN THE PRESENCE OF CERIA NANOPARTICLES.

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بازدید 141

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اطلاعات دوره: 
  • سال: 

    2023
  • دوره: 

    10
  • شماره: 

    4
  • صفحات: 

    281-290
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    24
  • دانلود: 

    0
چکیده: 

Solid oxide fuel cells are a technology that can convert chemical energy directly into electrical energy. In the present study, single-phase lanthanium strontium manganate (LSM) nanoparticles with the nominal chemical formula La0. 8Sr0. 2MnO3 were successfully synthesized by the improved Pechini method. The infiltration of heterogeneous copper and cerium electrocatalysts on the Cathode was investigated. X-ray diffraction (XRD) was used to determine the phase composition. The microstructure and surface morphology of the synthesized powder was characterized using a scanning electron microscope (SEM). The coated composition was examined using energy dispersive spectroscopy (EDS) and elemental mapping images. The microstructure of the electrocatalysts seeded on the Cathode was studied by FESEM. The infiltration of 0. 5 M copper + 0. 5 M cerium nanoparticles (dimensions from 23 to 52 nm) with a broad distribution on the LSM Cathode surface was obtained. Results showed that using single-component solutions of copper and cerium nanoparticles with dimensions of 39-61 nm and 20-42 nm, respectively, were generated on the Cathode surface. The formation of agglomerated particles was observed as the cerium solution concentration increased. Secondary copper growth was observed as the copper solution concentration increased.

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بازدید 24

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نویسنده: 

BABAEI A.

همایش: 

IRANIAN FUEL CELL SEMINAR

اطلاعات دوره: 
  • سال: 

    2012
  • دوره: 

    5
تعامل: 
  • بازدید: 

    139
  • دانلود: 

    0
چکیده: 

PERFORMANCE STABILITY OF LA0.8SR0.2MNO3 (LSM) Cathode PROMOTED WITH PALLADIUM CATALYST NANO-PARTICLES WAS INVESTIGATED AT CATALYST LOADINGS OF 0.08 MG CM-2 AND 0.25 MG CM-2 AND OPERATING TEMPERATURES OF 750 AND 850OC. ADDITION OF 0.08 MG CM-2 PDO TO THE MICROSTRUCTURE OF LSM ELECTRODE CONSIDERABLY DECREASED THE Cathode OVERPOTENTIAL FROM ABOUT 130 TO 21 MV AND THE PERFORMANCE OF THE CELL WAS QUITE REASONABLE DURING 44 H POLARIZATION OF THE CELL. THE HIGHER CATALYST LOADING OF 0.25 MG CM-2 WAS DETRIMENTAL TO THE PERFORMANCE STABILITY, ESPECIALLY AT HIGHER OPERATING TEMPERATURE OF 850OC. THE INSTABILITY OF THE CELL WAS MAINLY DUE TO THE AGGLOMERATION AND GRAIN GROWTH OF THE PDO CATALYST NANO PARTICLES AT THE SOLID OXIDE FUEL CELL (SOFC) OPERATION TEMPERATURE.

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بازدید 139

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نویسنده: 

Tamaddon H. | MAGHSOUDIPOUR A.

همایش: 

IRANIAN FUEL CELL SEMINAR

اطلاعات دوره: 
  • سال: 

    2012
  • دوره: 

    5
تعامل: 
  • بازدید: 

    152
  • دانلود: 

    0
چکیده: 

POROUS LA0.8SR0.2MNO3 Cathode MATERIALS WERE PREPARED BY MECHANOCHEMICAL ROUT IN VARIOUS GRINDING TIMES. CARBON BLACK WAS EMPLOYED TO PRODUCE PORES. THE FORMATION OF LSM SINGLE PHASE WAS STUDIED BY X-RAY DIFFRACTION PATTERNS. POROSITY AND DENSITY AMOUNT WAS MEASURED BY MEANS OF ARCHIMEDES METHOD, ALSO CONTRACTION OF SINTERED SAMPLES WAS COMPARABLY MEASURED. FOR MORPHOLOGICAL STUDY THE SCANNING ELECTRON MICROSCOPY (SEM) IMAGES WERE USED. IT IS SHOWN THAT THE OPEN POROSITY GENERALLY DECREASES WITH INCREASING TEMPERATURE, BUT MILLING TIME GROWTH INCREASED THIS FACTOR. RELYING ON OPEN POROSITY AMOUNT AND DISTRIBUTION, RELATIVE DENSITY AND MICROSTRUCTURAL SCRUTINY THE PROPER SINTERING TEMPERATURE WAS DETERMINED. THE MICROSTRUCTURE INDICATES THAT THE GRAIN GROWS AS THE SINTERING TEMPERATURE INCREASES, WHICH LEADS TO THE DECREASE OF THE NUMBER OF OPEN PORES.

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بازدید 152

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اطلاعات دوره: 
  • سال: 

    2015
  • دوره: 

    3
  • شماره: 

    1
  • صفحات: 

    25-32
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    234
  • دانلود: 

    0
چکیده: 

In the present study, the effect of porosity on the Cathode microstructure (50: 50 wt. % LSM: YSZ) of a Solid Oxide Fuel Cell (SOFC) has been examined. A 3-D finite element method for Mixed Ionic and Electronic Conducting Cathodes (MIEC) is presented to study the effects of porosity on cell performance. Each microstructure was realized using the Monte Carlo approach with the isotropic type of growth rate. The effect of porosity on the Cathode of a solid oxide fuel cell involving the Three Phase Boundary Length (TPBL), electric conductivity of LSM phase, ionic conductivity of YSZ, mechanical behavior and tortuosity of the pore phase were explored in the present work. The Cathode having a porosity value between 31 and 34% revealed the maximum TPBL value as well as a high variation in the electrical conductivity of the LSM phase. Pore phase tortuosity was also decreased by increasing the porosity factor.

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بازدید 234

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نویسندگان: 

MARZBAND M. | ZAREH M.R. | TAVAKOLI A.

اطلاعات دوره: 
  • سال: 

    2008
  • دوره: 

    5
  • شماره: 

    16
  • صفحات: 

    49-58
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    546
  • دانلود: 

    0
چکیده: 

Linear electric motors can drive a linear motion load without intermediate gears, screws or crank shafts. A linear synchronous motor (LSM) is a linear motor in which the mechanical motion is in synchronism with the magnetic field, i.e. the mechanical speed is the same as the speed of traveling magnetic field. In this paper, we obtained the electromagnetic thrust developed by a salient-pole LSM.

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بازدید 546

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مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
اطلاعات دوره: 
  • سال: 

    1389
  • دوره: 

    4
تعامل: 
  • بازدید: 

    293
  • دانلود: 

    140
چکیده: 

لطفا برای مشاهده چکیده به متن کامل (PDF) مراجعه فرمایید.

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نویسنده: 

نعیمی علی اکبر

اطلاعات دوره: 
  • سال: 

    1389
  • دوره: 

    4
تعامل: 
  • بازدید: 

    362
  • دانلود: 

    216
چکیده: 

لطفا برای مشاهده چکیده به متن کامل (PDF) مراجعه فرمایید.

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بازدید 362

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اطلاعات دوره: 
  • سال: 

    1398
  • دوره: 

    8
  • شماره: 

    1
  • صفحات: 

    16-33
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    712
  • دانلود: 

    161
چکیده: 

بررسی موجودی زمین لغزش ها، تیپولوژی و توزیع فضایی آنها ابزارهای ضروری برای تحدید نشانه های فضایی و زمانی زمین لغزش ها است. هدف تحقیق حاضر بررسی حساسیت زمین لغزش حوضه کن با استفاده از شاخص آنتروپی و الگوریتم ماشین های پشتیبان بردار است. معیارهای موثر در بروز زمین لغزش در این تحقیق شامل توپوگرافی، شیب، جهت شیب، کاربری اراضی، لیتولوژی، فاصله از گسل، فاصله از آبراهه و فاصله از جاده هستند. لایه های مکانی پارامترهای اثرگذار به پایگاه مکانی داده وارد شده و استاندارد سازی معیارها انجام شد. هر یک از پارامترها با توجه به میزان تاثیر بر وقوع مخاطره لغزش، طبق نظرات کارشناسی امتیازدهی و به صورت رستری به عنوان لایه های اصلی در پهنه بندی حساسیت لغزش با استفاده از شاخص آنتروپی بکار گرفته شده اند. ماتریس آنتروپی برای هر یک از عوامل محاسبه و سپس در محیط GIS نقشه پهنه بندی حساسیت لغزش منطقه، تهیه شده است. در الگوریتم پشتیبان بردار از تابع حلقوی استفاده شده بر اساس این الگوریتم هر یک از لایه های موثر در بروز زمین لغزش وزن دهی شده و سپس لایه ها هم پوشانی شده و نقشه حساسیت زمین لغزش بر اساس الگوریتم پشتیبان بردار تهیه شده است. جهت اعتبار سنجی مدل ها، با استفاده از 30 درصد نقاط لغزشی، منحنی ROC، ترسیم و مساحت زیر منحنی (AUC) محاسبه شده است. نتایج اعتبار سنجی نشان داده که الگوریتم ماشین های پشتیبان بردار ((SVM-SIGMOID (AUC = 0. 91) در برآورد حساسیت زمین لغزش در منطقه مورد مطالعه نسبت به مدل شاخص آنتروپی (AUC= 0. 86) از صحت بیشتر و قابلیت اعتماد بالاتری برخوردار است.

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بازدید 712

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اطلاعات دوره: 
  • سال: 

    2007
  • دوره: 

    4
  • شماره: 

    1
  • صفحات: 

    89-106
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    368
  • دانلود: 

    0
چکیده: 

The doped perovskite oxides such as La0.65 Sr0.30 MnO3-δ (LSM), La0.70 Sr0.30 CoO3-δ (LSC), La0.65 Sr0.30 FeO3-δ (LSF), La0.65 Sr0.30 NiO3-δ (LSN) and La0.60 Sr0.40 Co0.20 Fe0.80 O3-δ (LSCF) are proposed as alternate Cathode materials for solid oxide fuel cells working at reduced temperature (<1073 K). The critical requirement for their applicability is their chemical compatibility in conjunction with an alternate solid electrolyte, La0.9 Sr0.1 Ga0.8 Mg0.2 O3-δ (LSGM) without any new phase formation. To understand the chemical reactivity between these two components, thoroughly mixed different Cathode and LSGM electrolyte (1:1 by wt.) powders were pressed as circular components and subjected to annealing at 1573 K for 3 h in air. XRD and SEM were used for the characterization of the annealed samples. XRD measurements revealed that no new secondary phases were formed in LSM, LSC, and LSF with LSGM mixtures whereas LSN and LSCF with LSGM resulted in the formation of new secondary phases after high temperature treatment. The sintering shrinkage for all the components (Cathode + electrolyte mixture) was also estimated. For comparison of data, the individual powders (Cathode/electrolyte) were also compacted and studied in the same manner. The obtained results are discussed keeping in view the requirements that the candidate Cathode material must meet out with respect to its chemical compatibility to qualify for the LSGM based ITSOFC systems at 1073 K.

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بازدید 368

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